Cooler

Cooler is the main villain in the fifth and sixth movies of the anime Dragon Ball Z, introduced as the older brother of Freeza, and the oldest son of King Cold. He was designed by Akira Toriyama, the original manga author. Like his brother, Cooler can push his body through transformations to increase his power. Although only two forms are seen, it is stated that Cooler possesses the same number of forms Freeza does, as well as a fifth and more powerful form.

He first travels to Earth in Cooler's Revenge to kill Goku, the Saiyan that defeated his brother Freeza. He ends up fighting Goku in his final form. Once transformed, he increases dramatically in size, speed, and strength; four horns grow to form a crown atop his head as spikes form on his forearms, and he now sports a facemask of sorts, hiding all facial features save his eyes, which are now red and pupiless.

In The Return of Cooler,

He makes cameo appearances in Fusion Reborn and Dragon Ball GT, when all villains escape from Hell.

(Source: Wikipedia)